Mining is the extraction of resources from the ground. In a way just collecting something from the ground is not mining, mining includes some work, e.g. digging, to get access to something. Obviously the resource was either material needed for tools, jewelry, daily life, or art. So the earliest mining efforts included flint, gold and gems, salt and coal, and ochre. Originally only resources which were used unprocessed were mined, especially only metalls in native form. The use of any material required the knowledge how to process it, the different eras were named Bronze Age, Iron Age, and so forth, because the knowledge resulted in items which were created with that technology and were found by the archaeologists in their excavations.
This little list is a list of show mines you can visit, where mining started before the Iron Age. It does not include the hundreds of sites which are not open to the public, or the sites which are unknown and only identified by the products which were made with the material mined there. We ended the list at the end of the Bronze Age because the Iron Age are the Romans, and they had an abundance of mines all over Europe and this list would become quite long. So the following mines were operated during Stone Age, for the production of flint, pigments for painting, or salt for living. Later copper and tin were mined.
|Ngwenya Mine||Eswatini||Iron Mine||43000 BP||the ancient mine is an archaeological site, named Lion Cavern, a small cavern located on the western side of the northern open cast|
|Feuersteinbergwerk von Abensberg-Arnhofen||Germany||Stone Age Flint Mine||7300 BP||in the course of 700 years 300 tonnes of high-quality flint material were mined|
|Salzbergwerk Hallstatt||Austria||Salt Mine||7000 BP||an object made of deer antlers was found 1838 in the so-called Kaiser-Josef-Stollen, which was presumably used to mine salt, was dated to be 7000 years old|
|Les minières de silex néolithique de Spiennes||Belgium||Stone Age Flint Mine||6350 BP||According to the UNESCO WHL this is the oldest mine in Europe.|
|De prehistorische vuursteenmijnen van Rijckholt - St. Geertruid||The Netherlands||Stone Age Flint Mine||6200-4650 BP||Neolithic flint mine assigned to the Michelsberg culture and the Stein group.|
|Mines Prehistòriques de Gavà||Spain||Stone Age Flint Mine||6000 BP||According to their publications this is the oldest mine in Europe.|
|Prahistoryczne Kopalnie Krzemienia w Krzemionkach||Poland||Stone Age Flint Mine||5400 BP||from around 5400 to 3600 BP, more than 4,000 shafts were driven into the earth near Krzemionki.|
|De prehistorische vuursteenmijnen van Rijckholt - St. Geertruid||Netherlands||Stone Age Flint Mine||5150 (±60) BP||this is the C14 dating of remains found in the mine, estimated operation 6200 to 4650 BP during the Michelsberg culture and the Stein group|
|Grimes Graves||Great Britain||Stone Age Flint Mine||4600 BP||flint was extracted in hundreds of pits between 4600 and 4300 BP|
|Clearwell Caves||Great Britain||Iron Mine||4,500 BP||the oldest tools found in the mine were dated 4,500 BP, it is estimated that mining for ochre began around 5000 BP|
|Schaubergwerk Sunnpau||Austria||Copper Mine||4000 BP||fire setting created one of the largest mines of that time|
|Great Orme Mines||Great Britain||Copper Mine||4000 to 2600 BP||the largest Bronze Age copper mine in the world, produced about 1,700 t of copper|
|Schaubergwerk Arthurstollen||Austria||Copper Mine||3700 BP||early copper mining during the Bronze Age|
|Ecton Mine Educational Centre||Great Britain||Copper Mine||3600 BP|